Loess surface grafted functional copolymer for removing basic fuchsin

Loess surface grafted functional copolymer for removing basic fuchsin
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黄土表面接枝功能共聚物去除碱性品红

DOI:
10.1039/c7ra00610a
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发表时间:
2017-03
期刊:
影响因子:
3.9
通讯作者:
Rong-Min Wang
Rong-Min Wang
中科院分区:
化学3区
文献类型:
--
作者:
Tingjun Lu;Li Wang;Yu-Feng He;Jing Chen;Rong-Min Wang

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以黄土粘土(LC)为原料,采用丙烯酰胺(AM)、对苯乙烯磺酸钠(StS)等功能单体和交联剂(N,N-亚甲基双丙烯酰胺:MBA)进行表面接枝共聚改性,得到LC表面接枝共聚物(LC-PAmS)。采用傅里叶变换红外光谱(FT-IR)、热重分析(TGA)和扫描电镜(SEM)对其结构和组成进行了表征。研究了一种新型低成本黄土基高分子吸附剂对碱性品红的吸附性能。在优化条件下,室温下40 min,去除率可达98.4%。并对其吸附机理进行了探讨。结果表明,吸附等温线符合Freundlich等温式,吸附动力学符合准二级动力学模型。综上所述,LC-PAmS是一种具有实际应用价值的高分子吸附剂。
Loess clay (LC), a very abundant clay with granules and high hydrophilicity, was modified by surface grafting copolymerization of functional monomers, such as acrylamide (AM) and sodium p-styrene sulfonate (StS), and a cross-linking agent (N,N-methylenebisacrylamide: MBA), which afforded a LC surface grafting copolymer (LC-PAmS). Its structure and composition were characterized by Fourier transform infrared spectroscopy (FT-IR), thermal gravimetric analysis (TGA) and scanning electron microscopy (SEM). Acting as a novel and low-cost Loess-based polymer adsorbent, its adsorption behaviors were investigated with removing basic fuchsin (BF) in aqueous solution. After optimizing conditions, the removal rate got to 98.4% in 40 min at room temperature. Its adsorption mechanism was also investigated. It was found that the adsorption isotherm model could meet the Freundlich isotherm requirements and the dynamics were consistent with a pseudo-second-order kinetic model. In summary, LC-PAmS is a kind of polymer adsorbent for practically applied in wastewater treatment.
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