Ruthenium carbene complexes with imidazolin-2-ylidene ligands allow the formation of tetrasubstituted cycloalkenes by RCM

Ruthenium carbene complexes with imidazolin-2-ylidene ligands allow the formation of tetrasubstituted cycloalkenes by RCM
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DOI:
10.1016/s0040-4039(99)00919-3
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发表时间:
1999-06-25
影响因子:
1.8
通讯作者:
Herrmann, WA
Herrmann, WA
中科院分区:
化学4区
文献类型:
--
作者:
Ackermann, L;Fürstner, A;Herrmann, WA

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Chemically quite robust ruthenium carbene complexes 2-8 bearing one or two imidazolin-2-ylidene ligands are highly active catalysts for all types of ring closing metathesis reactions (RCM). Importantly, they even allow the formation of tetrasubstituted alkenes that were previously out of reach of ruthenium-based metathesis catalysts. (C) 1999 Elsevier Science Ltd. All rights reserved.