Deactivation of Q-cadmium sulfide photoluminescence through polynucleotide surface binding

Deactivation of Q-cadmium sulfide photoluminescence through polynucleotide surface binding
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DOI:
10.1021/j100205a001
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发表时间:
1992-12
期刊:
The Journal of Physical Chemistry
影响因子:
--
通讯作者:
S. R. Bigham;J. Coffer
S. R. Bigham;J. Coffer
中科院分区:
其他
文献类型:
--
作者:
S. R. Bigham;J. Coffer

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通过光致发光(PL)光谱研究了氢氧化镉层状Q-CdS团簇与多核苷酸之间的内在相互作用。对于平均直径为40埃且发光最大值在480 nm附近的半导体簇,可以通过添加多核苷酸如来自大肠杆菌的脱氧核糖核酸(DNA)来实现这种发射的猝灭。大肠杆菌或聚腺苷酸(poly[A])
The intrinsic interaction between cadmium hydroxide-layered Q-CdS clusters and polynucleotides has been examined via photoluminescence (PL) spectroscopy. For semiconductor clusters of 40-A average diameter and a narrow luminescence maximum near 480 nm, quenching of this emission can be accomplished by the addition of polynucleotides such as deoxyribonucleic acid (DNA) from E. coli or polyadenylic acid (poly[A])