Greening the Wacker process

Greening the Wacker process
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DOI:
10.1016/j.tetlet.2013.01.082
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发表时间:
2013-05-08
影响因子:
1.8
通讯作者:
Dhatrak, Nagorao R.
Dhatrak, Nagorao R.
中科院分区:
化学4区
文献类型:
--
作者:
Kulkarni, Mukund G.;Shaikh, Yunnus B.;Dhatrak, Nagorao R.

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Wacker oxidation of various terminal olefins with Pd-0/C-KBrO3, a nontoxic, environmentally benign, and easy to handle catalyst system, was achieved in high isolated yields. The described protocol offers an alternative to the traditional Wacker system which uses CuCl2 as co-catalyst. The catalyst is reusable while maintaining high activity and selectivity. (C) 2013 Elsevier Ltd. All rights reserved.