STUDY ON A4BX6 COMPOUNDS .2. REFINEMENT OF THE STRUCTURE OF RB4PBBR6 AND A NOTE ON THE EXISTENCE OF RB4HGL6 AND K4CDL6
STUDY ON A4BX6 COMPOUNDS .2. REFINEMENT OF THE STRUCTURE OF RB4PBBR6 AND A NOTE ON THE EXISTENCE OF RB4HGL6 AND K4CDL6
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DOI：
10.1002/zaac.19885620112
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发表时间：
1988-07-01
影响因子：
1.4
通讯作者：
MILIUS, W
中科院分区：
文献类型：
--
作者：
BECK, HP;MILIUS, W
用单晶数据(a=1332.9(4)，c=1647.8(5)pm；空间群R3c；K4CdCl6型排列)合成了Rb4PbBr6。合成Rb4HgI6和K4CdI6的尝试都没有成功。根据A4BX6化合物的结构场图对计算结果进行了讨论。
Rb4PbBr6was prepared by solid state reaction of the binary compounds and the structure refined with single crystal data (a = 1332.9(4), c = 1647.8(5) pm; space group R3c; K4CdCl6‐type arrangement). Attempts to synthesize Rb4HgI6and K4CdI6were unsuccessful. The results are discussed on the basis of a structure field diagram for A4BX6compounds.