On the orientational and rotational disorder in molecular crystals
On the orientational and rotational disorder in molecular crystals
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关于分子晶体的取向和旋转无序
DOI：
10.1524/zkri.1959.112.jg.234
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发表时间：
1959
期刊：
影响因子：
--
通讯作者：
I. Nitta
中科院分区：
文献类型：
--
作者：
I. Nitta
对于赝单原子、双原子、赝双原子、四面体和八面体分子的晶体，在熔点以下第一相具有取向或旋转无序的结构，已被调查与它们的熔化熵的大小有关。关于面心立方和体心立方类型的主要结构，似乎有一定的晶体化学规律。
For crystals of pseudo-monatomic, diatomic, pseudo-diatomic, tetrahedral and octahedral molecules, the structures with some orientational or rotational disorder of the first phase below the melting point have been surveyed in connection with the magnitude of their entropies of melting. There seems to be a certain crystal-chemical regularity as to the predominant structures of the facecentred cubic and body-centred cubic types.