Metallic interconnects for solid oxide fuel cell: A review on protective coating and deposition techniques

Metallic interconnects for solid oxide fuel cell: A review on protective coating and deposition techniques
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DOI:
10.1016/j.ijhydene.2016.03.195
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发表时间:
2017-04-06
影响因子:
7.2
通讯作者:
Ghazali, Mariyam J.
Ghazali, Mariyam J.
中科院分区:
工程技术2区
文献类型:
--
作者:
Mah, Joelle C. W.;Muchtar, Andanastuti;Ghazali, Mariyam J.

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随着固体氧化物燃料电池(SOFC)工作温度降低到600℃-800℃,传统的陶瓷互连线被用高抗氧化性的金属合金取代。在可制造性、成本、机械强度和导电性方面,金属互连比陶瓷互连更具优势。到目前为止,有希望用于金属互连的候选材料都是含铬合金,它们很容易发生挥发性铬迁移,导致电池退化。因此,保护性涂层已经被开发出来,以有效地抑制铬的迁移,同时保持良好的导电性和良好的抗氧化性。本文综述了金属互连发展的进展和技术挑战,以及中温SOFC应用中金属互连的不同类型的保护涂层和沉积技术。(C)2016年氢能源出版有限责任公司。爱思唯尔有限公司出版。保留所有权利。
With the reduction of solid oxide fuel cells (SOFCs) operating temperature to the range of 600 degrees C-800 degrees C, metallic alloy with high oxidation resistance are used to replace traditional ceramic interconnects. Metallic interconnects is advantageous over ceramic interconnects; in terms of manufacturability, cost, mechanical strength, and electrical conductivity. To date, promising candidates for metallic interconnects are all Cr-containing alloys, which are susceptible to volatile Cr migration that causes cell degradation. As such, protective coatings have been developed to effectively inhibit Cr migration; as well as maintain excellent electrical conductivity and good oxidation resistance. This article reviews the progress and technical challenges in developing metallic interconnects; different types of protective coatings and deposition techniques for metallic interconnects for intermediate temperature SOFC applications. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.