Molar heat capacity and thermodynamic properties of crystalline Eu(C2H5O2N)2Cl3·3H2O

Molar heat capacity and thermodynamic properties of crystalline Eu(C2H5O2N)2Cl3·3H2O
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DOI:
10.1007/s10973-012-2780-x
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发表时间:
2013-08
影响因子:
4.4
通讯作者:
X. Lv;Z. Tan;X. Gao;Lx Sun
X. Lv;Z. Tan;X. Gao;Lx Sun
中科院分区:
工程技术3区
文献类型:
--
作者:
X. Lv;Z. Tan;X. Gao;Lx Sun

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A complex of europium hydrochloric acid coordinated with 2-aminoacetic acid (C2H5O2N), Eu(C2H5O2N)2Cl3·3H2O was synthesized and characterized by IR and elements analysis. The heat capacities of the complex was measured with an automatic adiabatic calorimeter, and the thermodynamic functions [HT−H298.15] and [ST−S298.15] were derived in the temperature range from 80 to 340 K with temperature interval of 5 K. Thermal decomposition behavior of the complex in nitrogen atmosphere was studied by thermogravimetric (TG) analysis and differential scan calorimeter (DSC).