FeCp(CO)2I: A Phosphine-Free Half-Metallocene-Type Iron(II) Catalyst for Living Radical Polymerization of Styrene1
FeCp(CO)2I: A Phosphine-Free Half-Metallocene-Type Iron(II) Catalyst for Living Radical Polymerization of Styrene1
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DOI：
10.1021/ma9906130
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发表时间：
1999-09
期刊：
影响因子：
5.5
通讯作者：
Yuzo Kotani;M. Kamigaito;M. Sawamoto
中科院分区：
文献类型：
--
作者：
Yuzo Kotani;M. Kamigaito;M. Sawamoto
Introduction. The synthesis of polymers with precisely controlled molecular weights has been an important goal in polymer chemistry, which has been achieved via ionic and coordination polymerizations. In this and other aspects radical polymerization has been behind them despite its versatility. However, in these several years living radical polymerization has come true by varying methods. Among them, transition-metal catalysis is one of the most powerful approaches to control radical polymerization, because the activity of the catalyst can be designed by the combination of transition metals and appropriate ligands in response to the structure of monomers. 2
