MASS SPECTROMETRIC STUDY OF SUBLIMING SELENIUM
MASS SPECTROMETRIC STUDY OF SUBLIMING SELENIUM
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升华硒的质谱研究
DOI：
10.1139/v66-448
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发表时间：
1966
影响因子：
1.1
通讯作者：
A. Tickner
中科院分区：
文献类型：
--
作者：
H. Fujisaki;J. B. Westmore;A. Tickner
在102 ~ 187℃温度范围内升华的灰硒蒸气的质谱中，检测到n = 1 ~ n = 8之间所有可能的Sen+离子。Se5+、Se6+、Se7+和Se8+离子主要是由相应的母体分子电离产生的，被认为是环状的。175℃时，蒸汽组分为Se5≤29.0%,Se6≥57.5%,Se7≥11.4%,Se8≥2.0%。报道了这些分子升华的热力学数据。少量的Se9+和Se10+也被检测到。
In the mass spectrum of the vapor from grey selenium subliming in the temperature range 102 to 187 °C all possible Sen+ ions between n = 1 and n = 8 were detected in measurable quantities. The ions Se5+, Se6+, Se7+, and Se8+ arise mainly from ionization of the corresponding parent molecules, which are believed to be cyclic. At 175 °C the composition of the vapor is Se5 ≤ 29.0%, Se6 ≥ 57.5%, Se7 ≥ 11.4%, and Se8 ≥ 2.0%. Thermodynamic data are reported for the sublimation of these molecules. Small amounts of Se9+ and Se10+ were also detected.