n-Bu4NI-catalyzed direct amination of ethers with aryl tetrazoles and triazoles via cross-dehydrogenative coupling reaction
n-Bu4NI-catalyzed direct amination of ethers with aryl tetrazoles and triazoles via cross-dehydrogenative coupling reaction
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DOI：
10.1039/c5cy00229j
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发表时间：
2015-04
影响因子：
5
通讯作者：
Liang Wang;Kai-qiang Zhu;Wenting Wu;Qun Chen;Mingyang He
中科院分区：
文献类型：
--
作者：
Liang Wang;Kai-qiang Zhu;Wenting Wu;Qun Chen;Mingyang He
以四丁基碘化铵(TBAI)为催化剂，叔丁基氢过氧化氢(t-BuOOH)为氧化剂，开发了一种高效、无金属的芳基四氮唑和三氮唑直接胺化反应方法。在该体系中可以容忍一系列的醚、芳基四氮唑以及三氮唑，从而以中等到良好的产率得到相应的产品。
An efficient, metal-free protocol for direct amination of ethers with aryl tetrazoles and triazoles has been developed using tetrabutylammonium iodide (TBAI) as a catalyst and tert-butyl hydroperoxide (t-BuOOH) as an oxidant. A series of ethers, aryl tetrazoles as well as triazoles are tolerated in this system, giving the corresponding products in moderate to good yields.