From molecular mechanochemistry to stress-responsive materials
From molecular mechanochemistry to stress-responsive materials
复制标题
DOI：
10.1039/c0jm02636k
复制
发表时间：
2011-01-01
影响因子：
--
通讯作者：
Craig, Stephen L.
中科院分区：
文献类型：
--
作者：
Black, Ashley L.;Lenhardt, Jeremy M.;Craig, Stephen L.
综述了机械力化学活性官能团(“机械团”)与聚合物结合的研究现状和发展前景。这一研究领域是在两个类别的背景下处理的。第一类是为材料科学服务的新化学的发展，通过设计和合成机械载体来在材料中提供应力传感和/或应力响应元件。第二类是相反的--开发新的材料结构，将宏观作用力有效地传递到目标分子，以便产生其他方法无法获得的化学反应。
Current activity in, and future prospects for, the incorporation of mechanochemically active functional groups ("mechanophores") into polymers is reviewed. This area of research is treated in the context of two categories. The first category is the development of new chemistry in the service of material science, through the design and synthesis of mechanophores to provide stress-sensing and/or stress-responsive elements in materials. The second category is the reverse-the development of new material architectures that efficiently transmit macroscopic forces to targeted molecules in order to generate chemical reactivity that is inaccessible by other means.