Steric control of conformation in self-assembly metallacalix[4]arenes derived from AlMe3 or GaMe3 with benzimidazolyl ligands.
Steric control of conformation in self-assembly metallacalix[4]arenes derived from AlMe3 or GaMe3 with benzimidazolyl ligands.
复制标题
源自 AlMe3 或 GaMe3 与苯并咪唑基配体的自组装金属杯[4]芳烃中构象的空间控制。
作者：
Ernesto Rufino;M. Muñoz
通过自组装合成了金属杯[4]芳烃[bzimAlMe（2）]（4）（1），[bzimGaMe（2）]（4）（2），[mbzimAlMe（2）]（4）（3）和[mbzimGaMe（2）]（4）（4）。3和4的较大空腔使它们能够作为苯分子的宿主。
Metallacalix[4]arenes [bzimAlMe(2)](4) (1), [bzimGaMe(2)](4) (2), [mbzimAlMe(2)](4) (3) and [mbzimGaMe(2)](4) (4) were obtained by self-assembly. The larger cavity of 3 and 4 allows them to function as hosts of benzene molecules.