Opening size optimization of metal matrix in rolling-pressed activated carbon air-cathode for microbial fuel cells

Opening size optimization of metal matrix in rolling-pressed activated carbon air-cathode for microbial fuel cells
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微生物燃料电池压延活性炭空气阴极金属基体开孔尺寸优化

DOI:
10.1016/j.apenergy.2014.02.048
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发表时间:
2014-06-15
期刊:
影响因子:
11.2
通讯作者:
Zhou, Qixing
Zhou, Qixing
中科院分区:
工程技术1区
文献类型:
--
作者:
Li, Xiaojing;Wang, Xin;Zhou, Qixing

文献摘要

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研究了具有四种开口尺寸(20-80 M)的不锈钢网(SSM)作为微生物燃料电池(MFC)中活性炭空气阴极的基质。使用40 M获得了最高功率密度2151+/-109 mW m(-2)(5.54+/-0.14 A m(-2)),比80 M的1485+/-18 mW m(-2)高45%。线性扫描伏安法的趋势与阴极电位范围从-0.2到0的功率输出一致。五、业绩差异归因于内部因素 阻力。电荷转移电阻(R-ct)是大多数空气阴极中的主要内阻,在 40 M 中最低值为 2 52。与开口尺寸(R-2 = 0.7068)相比,金属网的密度与最大功率密度(R-2 = 0.9222)表现出更显着的相关性,这表明金属集流体的密度对阴极的性能至关重要。 (C) 2014 Elsevier Ltd. 保留所有权利。
Stainless steel mesh (SSM) with four opening sizes (20-80 M) were investigated as matrixes of activated carbon air-cathodes in microbial fuel cells (MFCs). The highest power density of 2151 +/- 109 mW m(-2) (at 5.54 +/- 0.14 A m(-2)) was obtained using 40 M, with a value 45% higher than 1485 +/- 18 mW m(-2) of 80 M. The trend of linear sweep voltammetries were in accordant with power output over a cathodic potential range from -0.2 to 0 V. The differences in performance were attributed to the internal resistances. Charge transfer resistance (R-ct) was the dominant internal resistance in most of air-cathodes, with the lowest value of 2 52 in 40 M. Density of metal mesh exhibited a more significant correlationship with maximum power densities (R-2 = 0.9222) compared to opening size (R-2 = 0.7068), demonstrated that the density of metal current collector was vital to the performance of cathodes. (C) 2014 Elsevier Ltd. All rights reserved.