THE TAUTOMERISM OF 1,2,3-TRIAZOLE IN AQUEOUS-SOLUTION
THE TAUTOMERISM OF 1,2,3-TRIAZOLE IN AQUEOUS-SOLUTION
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DOI：
10.1039/p29890001903
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发表时间：
1989-11-01
期刊：
影响因子：
--
通讯作者：
TAYLOR, PJ
中科院分区：
文献类型：
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作者：
ALBERT, A;TAYLOR, PJ
两个间接但独立的论点都证实了1,2,3-三唑的2h互变异构体在水溶液中以约2倍的倍数更有利。孤对斥力是可能的原因；讨论了溶剂依赖性的证据。
Two circumstantial but independent arguments both confirm that the 2H-tautomer of 1,2,3-triazole is favoured in aqueous solution by a factor of ca. two. Lone-pair repulsion is the probable cause; evidence from the solvent dependence of the tautomeric ratio is discussed.