Extreme redox variations in a superdeep diamond from a subducted slab
Extreme redox variations in a superdeep diamond from a subducted slab
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俯冲板片中超深钻石的极端氧化还原变化
DOI:
10.1038/s41586-022-05392-8
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发表时间:
2023
期刊:
影响因子:
64.8
通讯作者:
Bindi, Luca
中科院分区:
文献类型:
--
作者:
Nestola, Fabrizio;Regier, Margo E.;Luth, Robert W.;Pearson, D. Graham;Stachel, Thomas;McCammon, Catherine;Wenz, Michelle D.;Jacobsen, Steven D.;Anzolini, Chiara;Bindi, Luca
The introduction of volatile-rich subducting slabs to the mantle may locally generate large redox gradients, affecting phase stability, element partitioning and volatile speciation. Here we investigate the redox conditions of the deep mantle recorded in inclusions in a diamond from Kankan, Guinea. Enstatite (former bridgmanite), ferropericlase and a uniquely Mg-rich olivine (Mg# 99.9) inclusion indicate formation in highly variable redox conditions near the 660 km seismic discontinuity. We propose a model involving dehydration, rehydration and dehydration in the underside of a warming slab at the transition zone–lower mantle boundary. Fluid liberated by dehydration in a crumpled slab, driven by heating from the lower mantle, ascends into the cooler interior of the slab, where the H2O is sequestered in new hydrous minerals. Consequent fractionation of the remaining fluid produces extremely reducing conditions, forming Mg-end-member ringwoodite. This fractionating fluid also precipitates the host diamond. With continued heating, ringwoodite in the slab surrounding the diamond forms bridgmanite and ferropericlase, which is trapped as the diamond grows in hydrous fluids produced by dehydration of the warming slab.
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DOI:
--
发表时间:
2008
期刊:
European Journal of Mineralogy 20
影响因子:
--
作者:
Cayzer N.J.;Odake S.;Harte B.;Kagi H.
通讯作者:
Kagi H.
影响因子:
8.4
作者:
S. Shirey;L. Wagner;M. Walter;D. Pearson;P. V. van Keken
通讯作者:
S. Shirey;L. Wagner;M. Walter;D. Pearson;P. V. van Keken
影响因子:
18.3
作者:
E. Kiseeva;D. Vasiukov;B. Wood;C. McCammon;T. Stachel;M. Bykov;E. Bykova;A. Chumakov;V. Cerantola;J. Harris;L. Dubrovinsky
通讯作者:
E. Kiseeva;D. Vasiukov;B. Wood;C. McCammon;T. Stachel;M. Bykov;E. Bykova;A. Chumakov;V. Cerantola;J. Harris;L. Dubrovinsky
DOI:
--
发表时间:
2005
期刊:
影响因子:
--
作者:
R. Tappert;T. Stachel;J. Harris;N. Shimizu;G. Brey
通讯作者:
G. Brey
影响因子:
2.3
作者:
T. Kawamoto
通讯作者:
T. Kawamoto