Extreme redox variations in a superdeep diamond from a subducted slab

Extreme redox variations in a superdeep diamond from a subducted slab
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俯冲板片中超深钻石的极端氧化还原变化

DOI:
10.1038/s41586-022-05392-8
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发表时间:
2023
期刊:
影响因子:
64.8
通讯作者:
Bindi, Luca
Bindi, Luca
中科院分区:
综合性期刊1区
文献类型:
--
作者:
Nestola, Fabrizio;Regier, Margo E.;Luth, Robert W.;Pearson, D. Graham;Stachel, Thomas;McCammon, Catherine;Wenz, Michelle D.;Jacobsen, Steven D.;Anzolini, Chiara;Bindi, Luca

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富含挥发分的俯冲板引入地幔可能在局部产生较大的氧化还原梯度,影响相稳定性、元素分配和挥发分形态。在这里,我们研究了几内亚坎坎一颗钻石包裹体中记录的深部地幔的氧化还原条件。顽辉石(前桥镁辉石)、铁方镁石和独特的富镁橄榄石(MG#99.9)包裹体表明,在660 公里地震间断附近,形成于高度可变的氧化还原条件。我们提出了一个在过渡带-下地幔边界的升温板底的脱水、再水化和脱水的模型。在下地幔加热的推动下,在皱巴巴的板块中脱水释放的液体上升到板块较冷的内部,在那里H2O被隔离在新的含水矿物中。随后剩余流体的分馏作用产生了极强的还原条件,形成了含镁端元的环形木材。这种分馏流体还会沉淀出宿主钻石。随着持续的加热,钻石周围的板材中的环木石会形成桥锰矿和方镁铁,随着钻石在加温板材脱水产生的水合流体中生长,它们会被困住。
The introduction of volatile-rich subducting slabs to the mantle may locally generate large redox gradients, affecting phase stability, element partitioning and volatile speciation. Here we investigate the redox conditions of the deep mantle recorded in inclusions in a diamond from Kankan, Guinea. Enstatite (former bridgmanite), ferropericlase and a uniquely Mg-rich olivine (Mg# 99.9) inclusion indicate formation in highly variable redox conditions near the 660 km seismic discontinuity. We propose a model involving dehydration, rehydration and dehydration in the underside of a warming slab at the transition zone–lower mantle boundary. Fluid liberated by dehydration in a crumpled slab, driven by heating from the lower mantle, ascends into the cooler interior of the slab, where the H2O is sequestered in new hydrous minerals. Consequent fractionation of the remaining fluid produces extremely reducing conditions, forming Mg-end-member ringwoodite. This fractionating fluid also precipitates the host diamond. With continued heating, ringwoodite in the slab surrounding the diamond forms bridgmanite and ferropericlase, which is trapped as the diamond grows in hydrous fluids produced by dehydration of the warming slab.
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