Organised chaos: entropy in hybrid inorganic-organic systems and other materials.
Organised chaos: entropy in hybrid inorganic-organic systems and other materials.
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DOI：
10.1039/c6sc02199a
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发表时间：
2016-10-01
期刊：
影响因子：
8.4
通讯作者：
Kieslich G
中科院分区：
文献类型：
--
作者：
Butler KT;Walsh A;Cheetham AK;Kieslich G
熵是连接无机-有机杂化材料的灵活性和缺陷工程等新兴研究领域的基本量之一。在这里，我们强调了熵在过去的作用，并讨论了计算方法如何帮助我们理解未来无机-有机杂化材料中的熵效应。熵是连接无机-有机杂化材料的灵活性和缺陷工程等新兴研究领域的基本量之一。此外，熵和焓之间的微妙平衡可以导致此类材料中有趣的温度驱动转变。在这里，我们简要概述了传统的材料设计原理，强调了熵在过去的作用，并讨论了计算方法如何帮助我们理解和量化未来无机-有机杂化材料中的熵效应。
Entropy is one of the fundamental quantities which links emerging research areas like flexibility and defect engineering in inorganic–organic hybrid materials. Here, we highlight the role of entropy in the past and discuss how computational methods can help us to understand entropic effects in inorganic–organic hybrid materials in the future. Entropy is one of the fundamental quantities which links emerging research areas like flexibility and defect engineering in inorganic–organic hybrid materials. Additionally, a delicate balance between entropy and enthalpy can lead to intriguing temperature-driven transitions in such materials. Here, we briefly overview traditional material design principles, highlight the role of entropy in the past and discuss how computational methods can help us to understand and quantify entropic effects in inorganic–organic hybrid materials in the future.