A Bi/BiOCl heterojunction photocatalyst with enhanced electron-hole separation and excellent visible light photodegrading activity

A Bi/BiOCl heterojunction photocatalyst with enhanced electron-hole separation and excellent visible light photodegrading activity
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DOI:
10.1039/c3ta14494a
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发表时间:
2014-01-01
影响因子:
11.9
通讯作者:
Song, Weiguo
Song, Weiguo
中科院分区:
材料科学2区
文献类型:
--
作者:
Yu, Yu;Cao, Changyan;Song, Weiguo

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在可见光照射下,Bi/BiOCl异质结结构中的激发电子转移到氧空位态,然后转移到Bi金属纳米颗粒上,导致电子-空穴对的有效分离。该异质结光催化剂在光降解RhB染料和持久性有机污染物方面表现出非常高的活性,即RhB在2分钟内被完全降解。
Under visible light irradiation, excited electrons in heterojunction structure of Bi/BiOCl were transferred into oxygen vacancies states, and then to the Bi metal nanoparticles, resulting in effective separation of electron-hole pairs. The heterojunction photocatalyst exhibited an extraordinary high activity in photodegradation of RhB dye and persistent organic pollutants, i.e. RhB was completely degraded in 2 minutes.