Dendron-Containing Tetraphenylethylene Compounds: Dependence of Fluorescence and Photocyclization Reactivity on the Dendron Generation
Dendron-Containing Tetraphenylethylene Compounds: Dependence of Fluorescence and Photocyclization Reactivity on the Dendron Generation
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DOI：
10.1002/chem.201103675
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发表时间：
2012-03-01
影响因子：
4.3
通讯作者：
Zhang, Deqing
中科院分区：
文献类型：
--
作者：
Huang, Guangxi;Ma, Baode;Zhang, Deqing
合成和表征了四种含树枝状结构的四苯乙烯（TPE）1114，沿着一种含有四个OCH 2 Ph基团（称为10）的TPE化合物用于比较。光物理研究表明，TPE核心成为发射后，连接到其外围的树突。此外，当高代树突连接到TPE核心上时，荧光强度显著增强;荧光强度按以下顺序增加：11
The synthesis and characterization of four dendron-containing tetraphenylethylenes (TPEs), 1114, were synthesized, along with a TPE compound that contained four OCH2Ph groups (referred to as 10) for comparison. Photophysical studies revealed that the TPE core became emissive after linking dendrons onto its periphery. Moreover, the fluorescence intensity was significantly enhanced when high-generation dendrons were linked onto the TPE core; the fluorescence intensity increased in the following order: 11