Aqueous phase hydrogenation of levulinic acid to 1,4-pentanediol

Aqueous phase hydrogenation of levulinic acid to 1,4-pentanediol
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乙酰丙酸水相加氢生成1,4-戊二醇

DOI:
10.1039/c3cc48236g
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发表时间:
2014-01-01
影响因子:
4.9
通讯作者:
Cong, Yu
Cong, Yu
中科院分区:
化学2区
文献类型:
--
作者:
Li, Mengxia;Li, Guangyi;Cong, Yu

文献摘要

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首次发现Mo改性Rh/SiO2催化剂是乙酰丙酸水相选择加氢制1,4-戊二醇的有效催化剂。在该催化剂上,在低温(353 K)下,乙酰丙酸转化率(100%)和1,4-戊二醇收率(70%)可以达到。
For the first time, Mo modified Rh/SiO2 was found to be an effective catalyst for the aqueous phase selective hydrogenation of levulinic acid to 1,4-pentanediol. Over such a catalyst, high levulinic acid conversion (100%) and 1,4-pentanediol yield (70%) can be achieved at low temperature (353 K).