Reaction of dimethylvinylidene with γγ-dimethylallyl methyl sulphide. Synthesis of 2,5,5-trimethylhepta-2,6-dien-4-one (artemisia ketone)
Reaction of dimethylvinylidene with γγ-dimethylallyl methyl sulphide. Synthesis of 2,5,5-trimethylhepta-2,6-dien-4-one (artemisia ketone)
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DOI：
10.1039/c39740000010
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发表时间：
1974
期刊：
影响因子：
--
通讯作者：
D. Michelot;G. Linstrumelle;S. Julia
中科院分区：
文献类型：
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作者：
D. Michelot;G. Linstrumelle;S. Julia
The [2,3] sigmatropic rearrangement of the sulphonium ylide derived from the title reaction, followed by hydrolysis of the allenic thioether product affords artemisia ketone (6).
