An efficient synthesis of dibenzocycloocta-4a, 6a, -diene-5,11-diyne and its precursors
An efficient synthesis of dibenzocycloocta-4a, 6a, -diene-5,11-diyne and its precursors
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DOI：
10.1055/s-2002-32542
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发表时间：
2002-06
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影响因子：
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通讯作者：
S. Chaffins;M. Brettreich;F. Wudl
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文献类型：
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作者：
S. Chaffins;M. Brettreich;F. Wudl
采用已知反应，利用市售试剂制备了两种高效的二苯并环二烯二炔1的合成方法。这两种方法都是对已知合成的改进，总产率分别为41%和43%。后一种方法还提供了一种有效的合成二苯并环氯丁烯9的方法，这是目前商业上无法获得的关键试剂之一。
Two efficient syntheses of dibenzocyclooctadienediyne 1 were developed employing known reactions, which utilize commercially available reagents. Both methods are an improvement on known syntheses resulting in 41% and 43% overall yields. The latter method also offers an efficient synthesis of dibenzocyclooctateraene 9, which is one of the key reagents now commercially unavailable.