Synthesis of Optically Clear Molecular Organogels Comprising Phenol and Surfactants of Sulfosuccinic Acid Derivatives

Synthesis of Optically Clear Molecular Organogels Comprising Phenol and Surfactants of Sulfosuccinic Acid Derivatives
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DOI:
10.1246/cl.170540
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发表时间:
2017-06
期刊:
影响因子:
1.6
通讯作者:
K. Nishiyama;M. Ehara;S. Katsube;T. Kaji
K. Nishiyama;M. Ehara;S. Katsube;T. Kaji
中科院分区:
化学4区
文献类型:
--
作者:
K. Nishiyama;M. Ehara;S. Katsube;T. Kaji

文献摘要

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采用对氯苯酚(苯酚)和表面活性剂二(2-乙基己基)琥珀酸磺酯(AOT)制备有机凝胶。我们以前报道过苯酚+ AOT凝胶仅在环烷烃溶剂中光学透明,而在其他溶剂中具有高浊度。在发射器分散中,浑浊度可能引起不希望的光散射。在本研究中,AOT衍生物与琥珀酸酯上的三叉基和苯酚结合,形成了即使在芳香和无环溶剂中也是透明的凝胶。这些凝胶在整个可见区域都是透明的。
p-Chlorophenol (phenol) and the surfactant bis(2-ethylhexyl)sulfosuccinate (AOT) were used to produce organogels. We previously reported that phenol + AOT gels are optically clear only in cyclic alkane solvents but have high turbidity otherwise. In emitter dispersals, the turbidity may cause undesirable light scattering. Herein, an AOT derivative, with tridecyl groups attached to the succinic ester, and phenol were combined to form gels that are clear, even in aromatic and acyclic solvents. These gels are transparent over the entire visible region.