Measurements of atmospheric hydroperoxides over a rural site in central Japan during summers using a helicopter

Measurements of atmospheric hydroperoxides over a rural site in central Japan during summers using a helicopter
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DOI:
10.1016/j.atmosenv.2016.06.074
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发表时间:
2016-12
影响因子:
5
通讯作者:
Koichi Watanabe;C. Yachi;Miyuki Nishibe;Serina Michigami;Y. Saito;Nagisa Eda;N. Yamazaki;Taiki(平井泰貴) Hirai
Koichi Watanabe;C. Yachi;Miyuki Nishibe;Serina Michigami;Y. Saito;Nagisa Eda;N. Yamazaki;Taiki(平井泰貴) Hirai
中科院分区:
环境科学与生态学2区
文献类型:
--
作者:
Koichi Watanabe;C. Yachi;Miyuki Nishibe;Serina Michigami;Y. Saito;Nagisa Eda;N. Yamazaki;Taiki(平井泰貴) Hirai

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利用直升机对日本富山县伊米津市夏季H2 O2和MHP、O3、SO2和NOX* 浓度进行了观测。在采样后5-10 min内通过HPLC系统分析氢过氧化物的浓度。H2 O2浓度在地表最低,在海拔6000和8000英尺处检测到最高浓度。在高空大气中,MHP也较高。在从中国输送空气污染物时,观察到氢过氧化物的浓度非常高。在4000英尺以上,H2 O2的浓度高于SO2的浓度,此处水相中SO2氧化的潜在容量很大。直升机可用于在实验室中使用HPLC系统测量高空大气中的氢过氧化物。
The concentrations of hydroperoxides (H2O2and MHP), O3, SO2and NOX* over Imizu City, Toyama Prefecture, Japan were measured during summers using a helicopter. The concentrations of hydroperoxides were analyzed by an HPLC system within 5–10 min after the sampling. The H2O2concentration was lowest at the surface, and the highest concentration was detected at altitudes of 6000 and 8000 ft. The MHP was also higher in the high-altitude atmosphere. Significantly high concentrations of hydroperoxides were observed when air pollutants were transported from China. The concentration of H2O2was higher than that of SO2above 4000 ft where the potential capacity of SO2oxidation in the aqueous phase is large. A helicopter is useful for measuring of hydroperoxides in the high-altitude atmosphere using an HPLC system in a laboratory.