Transfer hydrogenation of aldehydes on amphiphilic catalyst assembled at the interface of emulsion droplets
Transfer hydrogenation of aldehydes on amphiphilic catalyst assembled at the interface of emulsion droplets
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DOI：
10.1039/b803209b
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发表时间：
2008-06
期刊：
影响因子：
9.8
通讯作者：
Jun Li;Yanmei Zhang;Difei Han;G. Jia;Jinbo Gao;Lin Zhong;Can Li
中科院分区：
文献类型：
--
作者：
Jun Li;Yanmei Zhang;Difei Han;G. Jia;Jinbo Gao;Lin Zhong;Can Li
在乳状液滴界面组装的两亲性聚合物基铱催化剂对水中醛类的转移加氢具有显著的加速作用，这可能是由于乳状液滴的高表面积和活性位点周围的高局部反应物浓度所致。
An amphiphilic polymer-based iridium catalyst assembled at the interface of emulsion droplets shows a remarkable rate acceleration for the transfer hydrogenation of aldehydes in water, which may result from the high surface area of the emulsion droplets and the high local concentrations of reactants around the active sites.