Mix-and-heat benzylation of alcohols using a bench-stable pyridinium salt
Mix-and-heat benzylation of alcohols using a bench-stable pyridinium salt
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DOI：
10.1021/jo0602773
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发表时间：
2006-05-12
影响因子：
3.6
通讯作者：
Dudley, GB
中科院分区：
文献类型：
--
作者：
Poon, KWC;Dudley, GB
2-苄氧基-1-甲基吡啶鎓三氟甲磺酸盐（1）是一种稳定的中性有机盐，在加热时将醇转化为苄醚。本文描述了1的合成和反应性。广泛的醇的苄基化以良好至优异的产率发生。
2-Benzyloxy-1-methylpyridinium triflate (1) is a stable, neutral organic salt that converts alcohols into benzyl ethers upon warming. The synthesis and reactivity of 1 are described herein. Benzylation of a wide range of alcohols occurs in good to excellent yield.