Rational design of benzodifuran-functionalized donor-acceptor covalent organic frameworks for photocatalytic hydrogen evolution from water†

Rational design of benzodifuran-functionalized donor-acceptor covalent organic frameworks for photocatalytic hydrogen evolution from water†
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DOI:
10.1039/d1cc00854d
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发表时间:
2021-03-30
影响因子:
4.9
通讯作者:
Dong, Yu-Bin
Dong, Yu-Bin
中科院分区:
化学2区
文献类型:
--
作者:
Wang, Guang-Bo;Zhu, Fu-Cheng;Dong, Yu-Bin

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合成了一种以苯并二呋喃为给体-受体的共价有机骨架,并将其用于模拟太阳光下的高效光催化析氢反应,在420 nm波长下,其具有上级稳定的析氢速率为1390 μ mol g(-1)h(-1),表观量子产率为7.8%。
A benzodifuran-based donor-acceptor covalent organic framework was synthesized and employed for efficient simulated sunlight-driven photocatalytic hydrogen evolution from water, which exhibited a superior and steady hydrogen evolution rate of 1390 mu mol g(-1) h(-1) and an outstanding apparent quantum yield (AQY) of 7.8% was obtained at 420 nm.