Kinetically controlled, high-yield synthesis of Au25 clusters
Kinetically controlled, high-yield synthesis of Au25 clusters
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DOI：
10.1021/ja0782448
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发表时间：
2008-01-30
影响因子：
15
通讯作者：
Jin, Rongchao
中科院分区：
文献类型：
--
作者：
Zhu, Manzhou;Lanni, Eric;Jin, Rongchao
发展了一种简便、低温、高产率合成Au-25团簇的方法。研究发现，通过控制Au(I)中间物种的形成动力学，可以实现单一尺寸团簇(Au-25)的排他性形成，这标志着单分散金团簇的合成取得了重要进展。
A facile, low-temperature method has been developed for synthesizing Au-25 clusters in high yield. It was discovered that by controlling the formation kinetics of the Au(I) intermediate species, exclusive formation of one-sized clusters (Au-25) can be achieved, which represents an important advance in the synthesis of monodisperse gold clusters.