DIELS-ALDER REACTIONS OF CYCLOALKENONES .1. PREPARATION AND STRUCTURE OF THE ADDUCTS

DIELS-ALDER REACTIONS OF CYCLOALKENONES .1. PREPARATION AND STRUCTURE OF THE ADDUCTS
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DOI:
10.1021/jo00147a003
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发表时间:
1982-01-01
影响因子:
3.6
通讯作者:
WENKERT, E
WENKERT, E
中科院分区:
化学2区
文献类型:
--
作者:
FRINGUELLI, F;PIZZO, F;WENKERT, E

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半个世纪以来,Diels-Alder反应一直是合成六元碳环的最佳方法之一。4二烯和亲二烯的环加成反应容易(例如,通过丙烯醛与1,3-丁二烯的相互作用生成1,2,5,6-四氢苯甲醛,如下图所示)。
For half a century the Diels-Alder reaction has served as one of the best methods of synthesis of six-membered carbocycles. 4 The ease of the cycloadditionof diene and dienophile (illustrated below, for example, by the pro-duction of 1, 2, 5, 6-tetrahydrobenzaldehyde from the interaction of acrolein with 1, 3-butadiene), the rapid accu-