Carbon acidity. 76. The remarkably low second pKa of 1-naphthylacetic acid. Lithium ion pair acidity in tetrahydrofuran
Carbon acidity. 76. The remarkably low second pKa of 1-naphthylacetic acid. Lithium ion pair acidity in tetrahydrofuran
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碳酸度。
DOI：
10.1021/ja00221a054
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发表时间：
1988
影响因子：
15
通讯作者：
A. Streitwieser
中科院分区：
文献类型：
--
作者：
S. Gronert;A. Streitwieser
A 1.38 0.648 22.13 B 2.25 0.642 22.05 C 1.38 0.738 22.12 D 2.50 0.821 21.97 E 4.02 3.02 21.83 F 3.59 3.16 21.82 G 4.65 4.08 21.76 H 2.90 5.71 21.73 I 3.77 6.38 21.74 J 3.39 9.36 21.66 K 2.75 11.6 21.66 L 2.33 11.4 21.62 M 5.20 14.5 21.65 N 2.44 15.6 21.45 O 3.07 17.3 21.54 P 10.6 8.22 21.99 Q 12.3 6.29 22.12 R 14.4 2.00 22.70“Concentrations in M. 6Measurements A, C, L, N, O against 9-n-butylfluorene (BuFl), pK= 22.36 (Gronert, S.; Streitwieser, A., Jr. J. Am. Chem. Soc. 1988, 110, 2836). Measurements B, DF, IK, M, PR against 9-benzyl-9-/f-benzo [d'e/] fluorene (BnMP), pK= 21.35. 19 Measurement G against 9-benzylfluorene (9-BnFl), pK= 21.36. 19
