A Co36 Cluster Assembled from the Reaction of Cobalt Pivalate with 2,3-Dicarboxypyrazine
A Co36 Cluster Assembled from the Reaction of Cobalt Pivalate with 2,3-Dicarboxypyrazine
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DOI：
10.1002/anie.200904743
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发表时间：
2009-01-01
影响因子：
16.6
通讯作者：
Rentschler, Eva
中科院分区：
文献类型：
--
作者：
Albores, Pablo;Rentschler, Eva
A record Co36 cluster is prepared. This mixed-valent compound containing CoII and CoIII centers is formed in the reaction of a dinuclear cobalt pivalate species with the polydentate 2,3-dicarboxypyrazine ligand. In terms of magnetic properties it behaves as a {Co16-Co16} supramolecular dimer in which the S = A spin ground states of each monomer do not interact.
