Efficient Base-Free Hydrogenation of Amides to Alcohols and Amines Catalyzed by Well-Defined Pincer Imidazolyl-Ruthenium Complexes
Efficient Base-Free Hydrogenation of Amides to Alcohols and Amines Catalyzed by Well-Defined Pincer Imidazolyl-Ruthenium Complexes
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DOI：
10.1021/acscatal.5b01955
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发表时间：
2016-01-01
期刊：
影响因子：
12.9
通讯作者：
Beller, Matthias
中科院分区：
文献类型：
--
作者：
Cabrero-Antonino, Jose R.;Alberico, Elisabetta;Beller, Matthias
合成了含咪唑氨基膦钳形配体的新型均相催化剂。该活性催化剂允许一系列酰胺在无碱条件下加氢，以高产率获得相应的醇和胺。
Novel homogeneous ruthenium catalysts bearing an imidazolylaminophosphino pincer ligand have been synthesized. The active catalyst allows for the hydrogenation of a range of amides under base-free conditions to afford the corresponding alcohols and amines in high yields.