Arraying Octahedral {Cr2Dy4} Units into 3D Single-Molecule-Magnet-Like Inorganic Compounds with Sulfate Bridges
Arraying Octahedral {Cr2Dy4} Units into 3D Single-Molecule-Magnet-Like Inorganic Compounds with Sulfate Bridges
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将八面体 {Cr2Dy4} 单元排列成具有硫酸盐桥的 3D 单分子磁体状无机化合物
DOI：
10.1021/acs.inorgchem.8b01210
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发表时间：
2018
影响因子：
4.6
通讯作者：
Zhu Dao-Ben
中科院分区：
文献类型：
--
作者：
Liu Cai-Ming;Zhang De-Qing;Hao Xiang;Zhu Dao-Ben
提出了两种基于[Cr2Dy4(μ4-O)2(μ3-OH)4]10+簇单元和硫酸根阴离子的新型3D纯无机化合物。两种配合物都表现出类似单分子磁体（SMM）的行为。类SMM团簇单元之间磁矩方向的排列对分子纳米磁体的性能影响显着，且方向一致性表现出明显的优势。
Two novel 3D pure inorganic compounds based on [Cr2Dy4(μ4-O)2(μ3-OH)4]10+cluster units and sulfate anions are presented. Both complexes exhibit single-molecule-magnet (SMM)-like behavior. Permutation of the magnetic moment direction among SMM-like cluster units has a significant effect on the performance of molecular nanomagnets, and directional consistency shows obvious advantages.