A laser flash photolysis study of p-tolyl(trifluoromethyl)carbene
A laser flash photolysis study of p-tolyl(trifluoromethyl)carbene
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DOI：
10.1039/a707586c
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发表时间：
1998-05-01
期刊：
影响因子：
--
通讯作者：
Crocker, PJ
中科院分区：
文献类型：
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作者：
Admasu, A;Gudmundsdottir, AD;Crocker, PJ
采用激光散列光解法（LFP）研究了3-对甲苯基-3-三氟甲基二嗪，得到了对甲苯基（三氟甲基）卡宾1的绝对动力学。得到了1与吡啶、酮类及有生物学意义的猝灭剂反应的绝对速率常数。讨论了这些数据和光亲和标记实验的意义。
3-p-Tolyl-3-trifluoromethyldiazirine was studied by laser hash photolysis (LFP) to obtain the absolute kinetics of p-tolyl(trifluoromethyl)carbene 1. The absolute rate constants for the reactions of 1 with pyridine, ketones and quenchers of biological interest were obtained. The implications of the data for photoaffinity labeling experiments are discussed.