Microwave-assisted synthesized SAPO-56 as a catalyst in the conversion of CO2 to cyclic carbonates.
Microwave-assisted synthesized SAPO-56 as a catalyst in the conversion of CO2 to cyclic carbonates.
复制标题
DOI：
10.1039/c3dt00064h
复制
发表时间：
2013-04
影响因子：
4
通讯作者：
Zhenzhen Xie;Minqi Zhu;Apolo Nambo;J. Jasinski;Moises A. Carreon
中科院分区：
文献类型：
--
作者：
Zhenzhen Xie;Minqi Zhu;Apolo Nambo;J. Jasinski;Moises A. Carreon
采用微波加热法合成了SAPO-56晶体。在CO2和环氧氯丙烷合成碳酸氯丙烯酯的反应中，该晶体表现出很高的催化活性。SAPO-56晶体的催化活性增强与其高的CO2吸附容量、小的晶体尺寸和酸中心的存在有关。
SAPO-56 crystals were synthesized via microwave heating. The resultant crystals displayed high catalytic activity in the synthesis of chloropropene carbonate from CO2 and epichlorohydrin. The enhanced catalytic activity of SAPO-56 crystals was related to their high CO2 adsorption capacity, small crystal size, and the presence of acid sites.