Alkoxide binding in inverse crown chemistry: rational synthesis of a series of composite alkali metal-magnesium-alkoxide-diisopropylamides
Alkoxide binding in inverse crown chemistry: rational synthesis of a series of composite alkali metal-magnesium-alkoxide-diisopropylamides
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DOI：
10.1039/b202549c
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发表时间：
2002-01-01
影响因子：
4.9
通讯作者：
Rowlings, RB
中科院分区：
文献类型：
--
作者：
Drewette, KJ;Henderson, KW;Rowlings, RB
通过将酰胺混合物与合适的醇反应，合理地合成了一系列通式为[{MMg[N（Pr-1）（2）]（2）OR}（2）]（其中M = Li，R = Oct（n）; M = Na，R = Bu-n或Oct（n））的锂-或钠-镁-二异丙基酰胺复合物。
A series of composite lithium- or sodium-magnesium-alkoxide-diisopropylamides of general formula [{MMg[N(Pr-i)(2)](2)OR}(2)] (where M = Li, R = Oct(n); M = Na, R = Bu-n or Oct(n)), has been synthesised rationally by treating synergic amide mixtures with the appropriate alcohol.