Rh(NHC)-Catalyzed Direct and Selective Arylation of Quinolines at the 8-Position
Rh(NHC)-Catalyzed Direct and Selective Arylation of Quinolines at the 8-Position
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DOI：
10.1021/ja111670s
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发表时间：
2011-03-23
影响因子：
15
通讯作者：
Chang, Sukbok
中科院分区：
文献类型：
--
作者：
Kwak, Jaesung;Kim, Min;Chang, Sukbok
建立了一种新的8位喹啉衍生物区域选择性直接芳基化反应的催化方法。该反应是由Rh(NHC)体系催化的，而NHC配体的选择是获得高反应活性和选择性的关键。
A new catalytic protocol for the regioselective direct arylation of quinoline derivatives at the 8-position has been developed. The reaction is catalyzed by a Rh(NHC) system, and the choice of the NHC ligand was most important for achieving high reactivity and selectivity.