Unusual face-to-face pi-pi stacking interactions within an indigo-pillared M3(tpt)-based triangular metalloprism.
Unusual face-to-face pi-pi stacking interactions within an indigo-pillared M3(tpt)-based triangular metalloprism.
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DOI：
10.1039/b809489f
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发表时间：
2008-11
影响因子：
4
通讯作者：
Jing‐Yun Wu;Che-Hao Chang;Che-Hao Chang;P. Thanasekaran;Chen-Chuan Tsai;Chen-Chuan Tsai;T. Tseng
中科院分区：
文献类型：
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作者：
Jing‐Yun Wu;Che-Hao Chang;Che-Hao Chang;P. Thanasekaran;Chen-Chuan Tsai;Chen-Chuan Tsai;T. Tseng
由Re 2（CO）10、2，4，6-三-4-吡啶基-1，3，5-三嗪（tpt，1）和靛蓝（H 2（2））自组装的三角金属棱柱[（（CO）3 Re（mu-2）Re（CO）3）3（mu 3 -1）2]，代表了一个相当新颖的例子，强大的面对面的pi，tpt配体的中心三嗪环之间的pi相互作用显着向内弯曲，使棱镜结构扭曲。
A triangular metalloprism, [((CO)3Re(mu-2)Re(CO)3)3(mu3-1)2], self-assembled from Re2(CO)10, 2,4,6-tri-4-pyridyl-1,3,5-triazine (tpt, 1), and indigo (H2(2)), represents a fairly novel example of strong face-to-face pi-pi interactions between the central triazine rings of the tpt ligands that bow significantly inward distorting the prismatic structure.