CO2-Responsive "Smart" Single-Walled Carbon Nanotubes

CO2-Responsive "Smart" Single-Walled Carbon Nanotubes
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二氧化碳响应“智能”单壁碳纳米管

DOI:
10.1002/adma.201202991
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发表时间:
2013-01-25
期刊:
影响因子:
29.4
通讯作者:
Wang, Yu
Wang, Yu
中科院分区:
材料科学1区
文献类型:
--
作者:
Guo, Zanru;Feng, Yujun;Wang, Yu

文献摘要

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A new type of "smart" single-walled carbon nanotubes is created by wrapping a pyrene-labeled CO2-responsive polymer via p-p stacking. The polymer/SWNT hybrids not only undergo a hydrophobic-hydrophilic transition upon CO2 stimulus in a mixed solvent, but also exhibit switchable dispersion/aggregation states upon the alternate bubbling of CO2 and N-2 in pure water.