Wetting of galvanized steel by Al 4043 alloys in the first cycle of CMT process

Wetting of galvanized steel by Al 4043 alloys in the first cycle of CMT process
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CMT 工艺第一周期中 Al 4043 合金对镀锌钢的润湿

DOI:
10.1016/j.jallcom.2013.11.177
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发表时间:
2014-03
影响因子:
6.2
通讯作者:
Lin, Qiaoli
Lin, Qiaoli
中科院分区:
材料科学2区
文献类型:
--
作者:
Zhou, Yanlin;Lin, Qiaoli

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Zn coating is essential for joining Al to galvanized steel by cold metal transfer (CMT) method; however the role of Zn on the wetting mechanism is still ambiguous. We recorded the first cycle for the molten metal transferring process using a high speed video camera, and further analyzed the wetting behavior and the interfacial microstructures. The results indicated that the significant contribution of Zn coating for the wetting is the reserved metallic characteristic of the galvanized steel surface after Zn evaporation. The residual liquid Zn film after evaporation could not improve the final wettability, and also should not be a driving force for spreading but may be a factor for contact angle hysteresis. Finally, a Zn rich zone was formed by the different affinity of Al–Fe, Zn–Fe and Al–Zn in thermodynamically, i.e., high affinity of Al–Fe and relative weak affinity of Zn–Fe and Zn–Al, and then the residual liquid Zn film was driven by the moving of molten Al alloys.
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