Preparation of Hybrid Ordered Inorganic–Organic Mesostructures from an Asymmetrically Bridged Organic Precursor Containing Both Silanolate and Phosphonate
Preparation of Hybrid Ordered Inorganic–Organic Mesostructures from an Asymmetrically Bridged Organic Precursor Containing Both Silanolate and Phosphonate
复制标题
由含有硅烷醇酯和膦酸酯的不对称桥接有机前体制备杂化有序无机-有机介观结构
DOI：
10.1246/cl.2010.496
复制
发表时间：
2010
影响因子：
1.6
通讯作者：
K. Maeda
中科院分区：
文献类型：
--
作者：
M. Otsu;T. Yamazaki;Y. Sasaki;K. Maeda
在阳离子表面活性剂存在下，以拟薄水铝石和同时含有硅酸酯和膦酸基的有机前驱体为原料，采用水热法制备了新型无机-有机杂化介孔结构。固体核磁共振分析表明，在所形成的二维六方介孔结构中，铝物种主要与膦酸基相连。
Novel hybrid inorganic-organic mesostructures were hydrothermally prepared from pseudo-boehmite and an organic precursor containing both silanolate and phosphonate groups in the presence of cationic surfactants. The solid-state NMR revealed that aluminum species are mainly connected with phosphonate groups in the formed 2D hexagonal mesostructures.