Thermochemical data of pure substances
Thermochemical data of pure substances
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DOI：
10.1002/9783527619825
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发表时间：
1989
期刊：
影响因子：
--
通讯作者：
I. Barin
中科院分区：
文献类型：
--
作者：
I. Barin
第一部分基本原则：热力学函数和关系-基本概念，热力学第一定律，焦耳-汤姆逊效应，热力学第二定律，热力学第三定律（能斯特热定理），热力学的基本关系，封闭系统与反应，化学势，化学平衡，混合物，吉布斯相律，电化学反应热化学函数的计算-单位和约定，计算纯物质的热化学函数，平衡计算，火用和熵平衡。第2部分热化学数据的编制和介绍：热化学数据的编制-基本热化学数据、现有汇编、热化学表。第3部分表在目前的工作：表格的准备-一般说明、数据来源、准确度、单位、标准状态、元素在298.15K和1巴时的参考相表格的结构-物质的排列、表格中相的顺序表格的内容和结构-公式、名称和相对摩尔质量、列表函数、温度顺序，相变、表中的最终温度、数据来源的参考、缩写和符号。第4部分表格使用示例：热力学计算示例-焓变、火用和熵平衡计算、平衡计算、具有多个相和组分的简化系统的平衡、电化学能量转换、高温燃料电池、多相平衡计算、多组分系统。第5部分表格信息：基本常数和换算系数-基本常数、能量单位换算系数、气体熵换算、基于A的元素相对原子质量12个，12 C。第6部分符号、缩略语和引用：表中所用的符号和缩略语表示表中数据的1巴引用。第七部分表：纯物质热化学数据表。
Part 1 Basic principles: thermodynamic functions and relations - the basic concepts, the first law of thermodynamics, Joule-Thomson effect, the second law of thermodynamics, the third law of thermodynamics (Nernst heat theorem), fundamental relations of thermodynamics, closed system with reactions, chemical potential, chemical equilibrium, mixtures, Gibbs phase rule, electrochemical reactions calculations of thermochemical functions - units and conventions, calculations of the thermochemical functions of pure substances, equilibrium calculations, exergy and entropy balances. Part 2 Compilation and presentation of thermochemical data: compilation of thermochemical data - basic thermochemical data, existing compilations, thermochemical tables. Part 3 Tables in the present work: preparation of the tables - general remarks, data sources, accuracy, units, standard states, reference phase for the elements at 298.15K and 1 bar construction of the tables - arrangement of substances, order of the phases in the tables contents and structure of the tables - formula, name and relative molar mass, tabulated functions, sequence of temperatures, phase transitions, the final temperature in the tables, references for the sources of data, abbreviations and symbols. Part 4 Examples of the use of the tables: examples of thermodynamic calculations - enthalpy changes, exergy and entropy balance calculations, equilibrium calculations, equilibrium in simplified systems with several phases and components, electrochemical energy conversion, high temperature fuel cell, the calculation of equilibria in multi-phases, multicomponent systems. Part 5 Information on the tables: fundamental constants and conversion factors - fundamental constants, conversion factors for energy units, conversions for entropies of gases, relative atomic masses of the elements based on A...=12 for 12C. Part 6 Symbols, abbreviations and references: symbols and abbreviations used in the tables reference phases of elements at 1 bar references for the data in the tables. Part 7 The tables: tables of thermochemical data of pure substances.