An Interpenetrated Framework Material with Hysteretic CO2 Uptake
An Interpenetrated Framework Material with Hysteretic CO2 Uptake
复制标题
DOI：
10.1002/chem.200902104
复制
发表时间：
2010-01-01
影响因子：
4.3
通讯作者：
Hupp, Joseph T.
中科院分区：
文献类型：
--
作者：
Mulfort, Karen L.;Farha, Omar K.;Hupp, Joseph T.
一种新的，双重互穿金属有机框架（MOF）材料已被合成，表现出显着的步骤，在吸附和滞后的解吸CO2的结构测量粉末X射线衍射（PXRD）和对分布函数（PDF）分析表明，结构变化CO2吸附后最有可能涉及互穿框架相对于彼此移动。
A new, twofold interpenetrated metal-organic framework (MOF) material has been synthesized that demonstrates dramatic steps in the adsorption and hysteresis in the desorption of CO2 Measurement of the structure by powder X-ray diffraction (PXRD) and pair distribution function (PDF) analysis indicates that structural changes upon CO2 sorption most likely involve the interpenetrated frameworks moving with respect to each other.