Preparation of Magnetic Ionic Liquids Composed of Hybrid-Type Anions
Preparation of Magnetic Ionic Liquids Composed of Hybrid-Type Anions
复制标题
DOI：
10.1071/ch12331
复制
发表时间：
2012-12
影响因子：
1.1
通讯作者：
Yumiko Takagi;Yoriko Kusunoki;Y. Yoshida;H. Tanaka;G. Saito;Kosuke Katagiri;T. Oshiki
中科院分区：
文献类型：
--
作者：
Yumiko Takagi;Yoriko Kusunoki;Y. Yoshida;H. Tanaka;G. Saito;Kosuke Katagiri;T. Oshiki
将1-乙基-3-甲基咪唑乙基硫酸盐([C2mim][EtSO4])与三氯化铁·6H2O混合得到杂化阴离子组成的磁性离子液体[C2mim][FeCl3·EtSO4]，其磁性与[C2mim][FeCl4]略有不同。另一方面，[C2mim][EtSO4]与氯化钴(II)水合物反应生成[C2mim]2[CoIICl4]，其结构经X-射线单晶分析表征。
1-Ethyl-3-methylimidazolium ethylsulfate ([C2mim][EtSO4]) was mixed with iron(III) chloride·6H2O to give a magnetic ionic liquid composed of the hybrid-type anion, [C2mim][FeCl3·EtSO4], which showed a slightly different magnetic property than [C2mim][FeCl4]. On the other hand, reaction of [C2mim][EtSO4] with cobalt(II) chloride hydrate formed [C2mim]2[CoIICl4], the structure of which was characterised by X-ray crystallographic analysis.