Suzuki cross-coupling reactions of potassium alkenyltrifluoroborates
Suzuki cross-coupling reactions of potassium alkenyltrifluoroborates
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DOI：
10.1021/ol0169729
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发表时间：
2002-01-10
期刊：
影响因子：
5.2
通讯作者：
Rivero, MR
中科院分区：
文献类型：
--
作者：
Molander, GA;Rivero, MR
GRAPHICSThe palladium-catalyzed coupling reaction of potassium alkenyltrifluoroborates with aryl or alkenyl halides or triflates proceeds readily with good yields. The trifluoroborates are air- and moisture-stable solids that can be stored indefinitely. The cross-coupling can be effected using PdCl2(dppf).CH2Cl2 as the catalyst in n-PrOH in the presence of Et3N. A variety of functional groups are tolerated.
