Bioinspired Catalysts with12Enzyme Functions

Bioinspired Catalysts with12Enzyme Functions
复制标题

具有 12 种酶功能的仿生催化剂

DOI：
10.1142/9789814307246_0020
复制
发表时间：
2010
期刊：
--
影响因子：
--
通讯作者：
H. Shimakoshi
H. Shimakoshi
中科院分区：
--
文献类型：
--
作者：
Y. Hisaeda;H. Shimakoshi

文献摘要

被引文献

相似文献

包括以下各节：缩略语清单i。引言A。酶反应B。B12模型复杂C。人工酶的构建2。生物启发的1，2-迁移反应A.1，2-钴络合物上官能团的迁移电化学1，2-官能团的迁移1。甲基丙二酰辅酶A突变的催化模拟2。1，2-官能团的催化迁移扩环反应C.由脱辅酶模型和B12模型组成的人工酶复合体1。甲基丙二酰辅酶A变位酶样反应2。谷氨酸变位酶样反应。其他碳-骨架重排反应III。生物启发的甲基转移反应A.甲基转移到烷基硫醇B。甲基转移到无机砷的研究IV.生物启发的脱卤化反应A.B12衍生物对有机卤化物的还原作用B12类化合物对有机卤化物的电催化还原B12衍生物对有机卤化物的光催化还原其他钴络合物对有机卤化物的脱氯研究生物灵感固定化催化剂A。B12改良电极B。非共价结合的B12修饰电极C。聚合物涂层B12改性电极D。共价结合的B12修饰电极E。B12固定化多聚体VI.其他生物启发的反应A.不对称反应B。其他反应七.结论八.参考文献
The following sections are included:List of AbbreviationsI. IntroductionA. Enzymic ReactionsB. B12Model ComplexesC. Construction of Artificial EnzymesII. Bioinspired 1,2-Migration ReactionsA. 1,2-Migration of Functional Groups on Cobalt ComplexesB. Electrochemical 1,2-Migration of Functional Groups1. Catalytic Simulation of Methylmalonyl-CoA Mutase2. Catalytic 1,2-Migration of Functional Groups3. Ring-Expansion ReactionsC. Artificial Enzymes Composed of Apoenzyme Model and B12Model Complexes1. Methylmalonyl-CoA Mutase-like Reactions2. Glutamate Mutase-like Reactions3. Other Carbon-Skeleton Rearrangement ReactionsIII. Bioinspired Methyl Transfer ReactionsA. Methyl Transfer to AlkylthiolsB. Methyl Transfer to Inorganic ArsenicsIV. Bioinspired Dehalogenation ReactionsA. Reduction of Organic Halides by B12DerivativesB. Electrocatalytic Reduction of Organic Halides by B12DerivativesC. Photocatalytic Reduction of Organic Halides by B12DerivativesD. Dechlorination of Organic Halides by Other Cobalt ComplexesV. Bioinspired Immobilized CatalystsA. B12Modified ElectrodesB. Noncovalently Bound B12Modified ElectrodesC. Polymer-coated B12Modified ElectrodesD. Covalently Bound B12Modified ElectrodesE. B12Immobilized PolymersVI. Other Bioinspired ReactionsA. Asymmetric ReactionsB. Other ReactionsVII. ConclusionsVIII. References