cis‐ versus trans‐Square‐Planar Palladium(II) and Platinum(II) Complexes with Triphenylphosphine Amino Acid Bioconjugates
cis‐ versus trans‐Square‐Planar Palladium(II) and Platinum(II) Complexes with Triphenylphosphine Amino Acid Bioconjugates
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顺式与反式方形平面钯 (II) 和铂 (II) 与三苯基膦氨基酸生物共轭物的配合物
DOI：
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发表时间：
2017
期刊：
影响因子：
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通讯作者：
S. Kirin
中科院分区：
文献类型：
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作者：
Zoran Kokan;B. Perić;G. Kovačević;A. Brozovic;N. Metzler‐Nolte;S. Kirin
合成了三苯基膦氨基酸生物偶联物Ph2P-pC6H4-Aaa-OR， Aa =甘氨酸（1G）、丙氨酸（2A）、缬氨酸（3V）、异亮氨酸（4I）、脯氨酸（5P）或苯丙氨酸（6F），并将其作为单齿配体制备了12种金属配合物[MCl2(Lig)2], M = Pd（II）或Pt（II）。所有制备的化合物都用光谱方法进行了表征，有些用x射线单晶衍射进行了表征，即配体1G和配合物1GPd、4IPd和6FPd。采用溶液核磁共振和计算方法研究了方形平面金属配合物的顺式和/或反式构型。
Triphenyphosphine amino acid bioconjugates Ph2P-pC6H4-Aaa-OR, Aa = glycine (1G), alanine (2A), valine (3V), isoleucine (4I), proline (5P) or phenylalanine (6F), have been synthesized and used as monodentate ligands for the preparation of twelve metal complexes, [MCl2(Lig)2], M = Pd(II) or Pt(II). All prepared compounds were characterized by spectroscopic methods, and in some cases by X-ray single crystal diffraction, namely for ligand 1G and complexes 1GPd, 4IPd and 6FPd. The cis- and / or trans- configuration of the square-planar metal complexes was investigated by solution NMR and computational methods.
影响因子：
62.1
作者：
Johnstone TC;Suntharalingam K;Lippard SJ
通讯作者：
Lippard SJ