(Me3Si)3SiH:: Twenty years after its discovery as a radical-based reducing agent
(Me3Si)3SiH:: Twenty years after its discovery as a radical-based reducing agent
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DOI：
10.1002/chem.200701415
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发表时间：
2008-01-01
影响因子：
4.3
通讯作者：
Chatgilialoglu, Chryssostomos
中科院分区：
文献类型：
--
作者：
Chatgilialoglu, Chryssostomos
这一概念显示了（Me3S）（3）SiH在几种合成转化中的灵活性和适用性，如自由基还原、连续自由基反应和硅氢化。（Me3Si）（3）SiH的反应性结合了物理有机化学和有机合成的多学科方面，延伸到聚合物和材料科学，如平面硅表面的功能化。
This Concept shows the flexibility and applicability Of (Me3S)(3)SiH in several synthetic transformations, such as radical reductions, consecutive radical reactions and hydrosilylation. The reactivity of (Me3Si)(3)SiH combines the multidisciplinary aspects of physical organic chemistry and organic synthesis, extending to polymers and materials science, as in the functionalization of flat silicon surfaces.