A non-metal catalysed oxidation of primary azides to nitriles at ambient temperature
A non-metal catalysed oxidation of primary azides to nitriles at ambient temperature
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DOI：
10.1039/c2ob06949k
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发表时间：
2012-01-01
影响因子：
3.2
通讯作者：
Prabhu, Kandikere Ramaiah
中科院分区：
文献类型：
--
作者：
Lamani, Manjunath;Devadig, Pradeep;Prabhu, Kandikere Ramaiah
在无溶剂条件下，以KI和DABCO为催化剂，在室温条件下，提出了一种新的非金属催化有机叠氮化物氧化制腈的方法。在此条件下，叠氮化物的双键和三键均未被氧化，具有良好的选择性。
A novel non-metal catalyzed oxidation of organic azides to nitriles under solvent-free conditions is presented employing catalytic amounts of KI, and DABCO in aq. TBHP at room temperature. This nonmetal catalyzed oxidation of azides provides good selectivity as double and triple bonds were not oxidized under the present reaction conditions.