Determination of boron by ion-pair liquid chromatography with 1,8-dihydroxynaphthalene-3,6-disulfonic acid

Determination of boron by ion-pair liquid chromatography with 1,8-dihydroxynaphthalene-3,6-disulfonic acid
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1,8-二羟基萘-3,6-二磺酸离子对液相色谱法测定硼

DOI:
10.1021/ac00260a048
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发表时间:
1983
影响因子:
7.4
通讯作者:
K. Tǒei
K. Tǒei
中科院分区:
化学1区
文献类型:
--
作者:
S. Motomizu;Ikuo. Sawatani;M. Oshima;K. Tǒei

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硼变色酸络合物形成的结果及讨论。缓冲溶液的pH值和浓度的影响。用醋酸盐缓冲溶液考察了pH对硼络合物形成的影响。在pH为4~5的范围内,峰高和峰面积几乎不变。考察了醋酸盐缓冲液(pH 4.8)的浓度。峰高和峰面积在0.01~0.3m范围内基本不变。
RESULTS AND DISCUSSION Formation of Boron-Chromotropic Acid Complex. Effect of pH and concentration of buffersolution. The effect of pH on the formation of boron complex was examined by using acetate buffer. The peak height and area were almost constant at pH region from 4 to 5. The concentration of acetate buffer (pH 4.8) was examined. The peak height and area were almost constant from 0.01 M to 0.3 M.